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Essay Galaxy - Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen's Catalyst
Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen's
Catalyst
Abstract. 1,2 diaminocyclohexane was reacted with L-(+)-tartaric acid to yield
(R,R)-1,2-diaminocyclohexane mono-(+)-tartrate salt. The tartrate salt was then
reacted with potassium carbonate and 3,5-di-tert-butylsalicylaldehyde to yield
(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, which was
then reacted with Mn(OAc)2*4H2O and LiCl to form Jacobsen's catalyst. The
synthesized Jacobsen's catalyst was used to catalyze the epoxidation of
dihydronaphthalene. The products of this reaction were isolated, and it was
found that the product yielded 1,2-epoxydihydronaphthalene as well as
naphthalene.
Introduction
In 1990, profe....
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Number Of Pages: 8 |
Number Of Words: 2180 |
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